What exactly is it you’re having problems with?
With Dreamhost, you still basically just need to “connect and upload your stuff” - is it that you’re not sure what information to put into Dreamweaver’s FTP settings? If so, check the e-mails you got when you first opened your account. One of them should have the settings. You just use your web address (www.yourdomain.com, without the http bit) as the FTP server, and the username and password you picked when you signed up, which should be in that e-mail. Just pick “New Site” in Dreamweaver, and enter the info under “Web Server” in the dialogue box that comes up. The “Local Root Folder” under “Local Info” will be the same as it was for your Angelfire site.
If there’s something else you’re having trouble with, just say what it is and someone should be able to help you. The knowledge base, at http://kbase.newdream.net, is also very helpful.